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aed_organic_matter.F90
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aed_organic_matter.F90
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!###############################################################################
!# #
!# aed_organic_matter.F90 #
!# #
!# Developed by : #
!# AquaticEcoDynamics (AED) Group #
!# School of Agriculture and Environment #
!# The University of Western Australia #
!# #
!# http://aquatic.science.uwa.edu.au/ #
!# #
!# Copyright 2013 - 2021 - The University of Western Australia #
!# #
!# GLM is free software: you can redistribute it and/or modify #
!# it under the terms of the GNU General Public License as published by #
!# the Free Software Foundation, either version 3 of the License, or #
!# (at your option) any later version. #
!# #
!# GLM is distributed in the hope that it will be useful, #
!# but WITHOUT ANY WARRANTY; without even the implied warranty of #
!# MERCHANTABILITY or FITNESS FOR A PARTICULAR PURPOSE. See the #
!# GNU General Public License for more details. #
!# #
!# You should have received a copy of the GNU General Public License #
!# along with this program. If not, see <http://www.gnu.org/licenses/>. #
!# #
!# ----------------------------------------------------------------------- #
!# #
!# Created June 2011 #
!# Track changes on GitHub @ https://github.com/AquaticEcoDynamics/libaed-water
!# #
!# #
!###############################################################################
! !
! .----------------. .----------------. .----------------. !
! | .--------------. || .--------------. || .--------------. | !
! | | ____ | || | ______ | || | ____ ____ | | !
! | | .' `. | || | .' ___ | | || ||_ \ / _|| | !
! | | / .--. \ | || | / .' \_| | || | | \/ | | | !
! | | | | | | | || | | | ____ | || | | |\ /| | | | !
! | | \ `--' / | || | \ `.___] _| | || | _| |_\/_| |_ | | !
! | | `.____.' | || | `._____.' | || ||_____||_____|| | !
! | | | || | | || | | | !
! | '--------------' || '--------------' || '--------------' | !
! '----------------' '----------------' '----------------' !
! !
!###############################################################################
#include "aed.h"
MODULE aed_organic_matter
!-------------------------------------------------------------------------------
! aed_organic_matter --- organic matter biogeochemical model
!
! The Organic Matter (OM) module contains equations for mineralisation
! and breakdown of particulate and dissolved organic matter pools, as well as
! settling, resuspension and other processes
!
! Users can optionally configure refractory pools
!-------------------------------------------------------------------------------
USE aed_core
USE aed_util,ONLY : water_viscosity
IMPLICIT NONE
PRIVATE ! By default make everything private
!
PUBLIC aed_organic_matter_data_t
!
TYPE,extends(aed_model_data_t) :: aed_organic_matter_data_t
!# Variable identifiers (OGM)
INTEGER :: id_poc, id_doc ! particulate & dissolved organic carbon
INTEGER :: id_pon, id_don ! particulate & dissolved organic nitrogen
INTEGER :: id_pop, id_dop ! particulate & dissolved organic phosphorus
INTEGER :: id_docr,id_donr,id_dopr ! dissolved refractory OM pools
INTEGER :: id_cpom ! coarse particulate OM (bulk) pool
INTEGER :: id_sed_pon, id_sed_don ! sediment ON pool
INTEGER :: id_sed_pop, id_sed_dop ! sediment OP pool
INTEGER :: id_sed_poc, id_sed_doc ! sediment OC pool
!# Variable identifiers (links)
INTEGER :: id_oxy, id_dic
INTEGER :: id_nit, id_no2, id_n2o, id_amm
INTEGER :: id_frp, id_fe, id_ch4, id_so4
INTEGER :: id_temp, id_salt, id_vis, id_uva, id_uvb, id_extc, id_rho, id_dz
INTEGER :: id_Psed_poc, id_Psed_pon, id_Psed_pop, id_Psed_cpom ! sedimentation rates
INTEGER :: id_Fsed_pon, id_Fsed_don ! sed. rate organic nitrogen
INTEGER :: id_Fsed_pop, id_Fsed_dop ! sed. rate organic phosphorus
INTEGER :: id_Fsed_poc, id_Fsed_doc ! sed. rate organic carbon
!# Variable identifiers (diags)
INTEGER :: id_pon_miner, id_don_miner
INTEGER :: id_pop_miner, id_dop_miner
INTEGER :: id_poc_miner, id_doc_miner
INTEGER :: id_swi_pon, id_swi_don
INTEGER :: id_swi_pop, id_swi_dop
INTEGER :: id_swi_poc, id_swi_doc
INTEGER :: id_docr_miner, id_donr_miner, id_dopr_miner
INTEGER :: id_sed_toc, id_sed_ton, id_sed_top
INTEGER :: id_l_resus, id_denit, id_anaerobic
INTEGER :: id_pom_vvel, id_cpom_vvel
INTEGER :: id_bod, id_cdom
INTEGER :: id_photolysis
!# Model options
INTEGER :: resuspension, settling
INTEGER :: simDenitrification,simFeReduction,simSO4Reduction,simMethanogenesis,simSedimentOM
LOGICAL :: simRPools,simPhotolysis
LOGICAL :: use_oxy,use_amm,use_frp,use_dic,use_nit,use_no2,use_n2o,use_fe3,use_ch4,use_so4
LOGICAL :: use_Fsed_link_don, use_Fsed_link_dop, use_Fsed_link_doc
LOGICAL :: use_Fsed_link_pon, use_Fsed_link_pop, use_Fsed_link_poc
LOGICAL :: use_Psed_link_pon, use_Psed_link_pop, use_Psed_link_poc
!# Model parameters
AED_REAL :: Rpoc_hydrol, Rpon_hydrol, Rpop_hydrol, &
Rdoc_minerl, Rdon_minerl, Rdop_minerl, Rdom_minerl, &
theta_hydrol, theta_minerl, Kpom_hydrol, Kdom_minerl, f_an
AED_REAL :: Rdomr_minerl, Rcpom_bdown, X_cpom_n, X_cpom_p
AED_REAL :: Ko2_0,Kin_denitrat,Kin_denitrit,Kin_denitrous,Klim_denitrous,Klim_denitrit,Kpart_denitrit
AED_REAL :: K_nit,K_so4,K_fe
AED_REAL :: KeDOM, KePOM, KeDOMR, KeCPOM, photo_fmin
AED_REAL :: w_pom, d_pom, rho_pom, w_cpom, d_cpom, rho_cpom
AED_REAL :: sedimentOMfrac, Xsc, Xsn, Xsp
AED_REAL :: Ksed_dom, theta_sed_dom, Fsed_doc, Fsed_don, Fsed_dop
CONTAINS
PROCEDURE :: define => aed_define_organic_matter
PROCEDURE :: calculate => aed_calculate_organic_matter
PROCEDURE :: calculate_benthic => aed_calculate_benthic_organic_matter
PROCEDURE :: mobility => aed_mobility_organic_matter
PROCEDURE :: light_extinction => aed_light_extinction_organic_matter
END TYPE
! MODULE GLOBALS
LOGICAL :: extra_diag = .false.
INTEGER :: diag_level = 10 ! 0 = no diagnostic outputs
! 1 = basic diagnostic outputs
! 2 = flux rates, and supporitng
! 3 = other metrics
!10 = all debug & checking outputs
AED_REAL :: c
!===============================================================================
CONTAINS
!###############################################################################
SUBROUTINE aed_define_organic_matter(data, namlst)
!-------------------------------------------------------------------------------
! Initialise the AED module
!
! Here, the aed namelist is read and the variables required
! by the module are registered for AED simulation.
!-------------------------------------------------------------------------------
!ARGUMENTS
INTEGER,INTENT(in) :: namlst
CLASS (aed_organic_matter_data_t),INTENT(inout) :: data
!
!LOCALS
INTEGER :: status
AED_REAL :: initial_sedom
! %% NAMELIST %% /aed_organic_matter/
! %% Last Checked 20/08/2021
!-- Default initial values and limits
AED_REAL :: om_min = zero_
AED_REAL :: om_max = 1e8
AED_REAL :: poc_initial = 100.0
AED_REAL :: doc_initial = 100.0
AED_REAL :: pon_initial = 16.0
AED_REAL :: don_initial = 16.0
AED_REAL :: pop_initial = 1.0
AED_REAL :: dop_initial = 1.0
AED_REAL :: docr_initial = zero_
AED_REAL :: donr_initial = zero_
AED_REAL :: dopr_initial = zero_
AED_REAL :: cpom_initial = zero_
!-- Breakdown and mineralisation (basic pool)
INTEGER :: simDenitrification = 0
INTEGER :: simFeReduction = 0
INTEGER :: simSO4Reduction = 0
INTEGER :: simMethanogenesis = 0
AED_REAL :: Rpom_hydrol = zero_
AED_REAL :: Rpoc_hydrol = zero_
AED_REAL :: Rpon_hydrol = zero_
AED_REAL :: Rpop_hydrol = zero_
AED_REAL :: Rdom_minerl = zero_
AED_REAL :: Rdoc_minerl = zero_
AED_REAL :: Rdon_minerl = zero_
AED_REAL :: Rdop_minerl = zero_
AED_REAL :: theta_hydrol = 1.0
AED_REAL :: theta_minerl = 1.0
AED_REAL :: Kpom_hydrol = 20.0
AED_REAL :: Kdom_minerl = 20.0
AED_REAL :: f_an = 1.0
AED_REAL :: Kin_denitrat = 20.0
AED_REAL :: Kin_denitrit = 0.297
AED_REAL :: Kin_denitrous = 0.205
AED_REAL :: K_nit = 1.
AED_REAL :: Klim_denitrous = 1.
AED_REAL :: Klim_denitrit = 1.
AED_REAL :: Kpart_denitrit = 1.
CHARACTER(len=64) :: denit_link = 'NIT_denit'
CHARACTER(len=64) :: dom_miner_oxy_reactant_var=''
CHARACTER(len=64) :: dom_miner_nit_reactant_var=''
CHARACTER(len=64) :: dom_miner_no2_reactant_var=''
CHARACTER(len=64) :: dom_miner_n2o_reactant_var=''
CHARACTER(len=64) :: dom_miner_fe3_reactant_var=''
CHARACTER(len=64) :: dom_miner_so4_reactant_var=''
CHARACTER(len=64) :: dom_miner_ch4_reactant_var=''
CHARACTER(len=64) :: doc_miner_product_variable=''
CHARACTER(len=64) :: don_miner_product_variable=''
CHARACTER(len=64) :: dop_miner_product_variable=''
!-- Refractory organic matter (optional)
LOGICAL :: simRPools = .false.
AED_REAL :: Rdomr_minerl = 0.001
AED_REAL :: Rcpom_bdown = 0.001
AED_REAL :: X_cpom_n = 16./106.
AED_REAL :: X_cpom_p = 1./106.
CHARACTER(len=64) :: docr_miner_product_variable='OGM_doc'
CHARACTER(len=64) :: donr_miner_product_variable='OGM_don'
CHARACTER(len=64) :: dopr_miner_product_variable='OGM_dop'
!-- Light related parameters
AED_REAL :: KeDOM = 0.0001
AED_REAL :: KePOM = 0.0001
AED_REAL :: KeDOMR = 0.0001
AED_REAL :: KeCPOM = 0.0001
AED_REAL :: photo_fmin = 0.9
AED_REAL :: photo_c = 7.52
LOGICAL :: simPhotolysis = .FALSE.
!-- Particle settling parameters
INTEGER :: settling = 0
AED_REAL :: w_pom = zero_
AED_REAL :: d_pom = zero_
AED_REAL :: rho_pom = zero_
AED_REAL :: w_cpom = zero_
AED_REAL :: d_cpom = zero_
AED_REAL :: rho_cpom = zero_
CHARACTER(len=64) :: Psed_poc_variable=''
CHARACTER(len=64) :: Psed_pon_variable=''
CHARACTER(len=64) :: Psed_pop_variable=''
CHARACTER(len=64) :: Psed_cpom_variable=''
!-- Sediment interaction parameters (basic model)
INTEGER :: resuspension = 0
INTEGER :: simSedimentOM = 0
AED_REAL :: sedimentOMfrac = zero_
AED_REAL :: sedimentBulkDens = 1.3e3
AED_REAL :: sedimentDepth = 0.5
AED_REAL :: Xsc = zero_
AED_REAL :: Xsn = zero_
AED_REAL :: Xsp = zero_
AED_REAL :: Fsed_doc = zero_
AED_REAL :: Fsed_don = zero_
AED_REAL :: Fsed_dop = zero_
AED_REAL :: Ksed_dom = zero_
AED_REAL :: theta_sed_dom = 1.0
CHARACTER(len=64) :: resus_link =''
CHARACTER(len=64) :: Fsed_poc_variable=''
CHARACTER(len=64) :: Fsed_doc_variable=''
CHARACTER(len=64) :: Fsed_pon_variable=''
CHARACTER(len=64) :: Fsed_don_variable=''
CHARACTER(len=64) :: Fsed_pop_variable=''
CHARACTER(len=64) :: Fsed_dop_variable=''
!-- From Module Globals
! LOGICAL :: extra_diag = .FALSE. !## Obsolete Use diag_level = 10
! INTEGER :: diag_level = 10 ! 0 = no diagnostic outputs
! ! 1 = basic diagnostic outputs
! ! 2 = flux rates, and supporitng
! ! 3 = other metrics
! !10 = all debug & checking outputs
! %% END NAMELIST %% /aed_organic_matter/
!-- Parameters to read in
NAMELIST /aed_organic_matter/ om_min, om_max, &
poc_initial,pon_initial,pop_initial, &
doc_initial,don_initial,dop_initial, &
docr_initial, donr_initial, dopr_initial, cpom_initial, &
Rpoc_hydrol,Rpon_hydrol,Rpop_hydrol,Rpom_hydrol, &
Rdoc_minerl,Rdon_minerl,Rdop_minerl,Rdom_minerl, &
theta_hydrol,theta_minerl,Kpom_hydrol,Kdom_minerl,f_an, &
dom_miner_oxy_reactant_var, dom_miner_nit_reactant_var, &
dom_miner_no2_reactant_var, dom_miner_n2o_reactant_var, &
dom_miner_fe3_reactant_var, dom_miner_so4_reactant_var, &
dom_miner_ch4_reactant_var, doc_miner_product_variable, &
don_miner_product_variable, dop_miner_product_variable, &
simRPools,Rdomr_minerl, &
Rcpom_bdown,X_cpom_n,X_cpom_p, &
Kin_denitrat,Kin_denitrit,Kin_denitrous,K_nit, &
Klim_denitrous,Klim_denitrit,Kpart_denitrit, &
KeDOM, KePOM, KeDOMR, KeCPOM, &
simPhotolysis, photo_fmin, photo_c, &
settling,w_pom,d_pom,rho_pom,w_cpom,d_cpom,rho_cpom, &
Psed_poc_variable, Psed_pon_variable, &
Psed_pop_variable,Psed_cpom_variable, &
resuspension, resus_link, &
sedimentOMfrac,sedimentBulkDens,sedimentDepth, &
Xsc,Xsn,Xsp, &
Fsed_doc,Fsed_don,Fsed_dop,Ksed_dom,theta_sed_dom, &
Fsed_poc_variable, Fsed_doc_variable, &
Fsed_pop_variable, Fsed_dop_variable, &
Fsed_pon_variable, Fsed_don_variable, &
simDenitrification, simFeReduction, &
simSO4Reduction, simMethanogenesis, simSedimentOM, &
extra_diag, diag_level
!-------------------------------------------------------------------------------
!BEGIN
print *," aed_organic_matter initialization"
! Default parameters set above at declaration
! Read the namelist
read(namlst,nml=aed_organic_matter,iostat=status)
IF (status /= 0) STOP 'Error reading namelist aed_organic_matter'
IF( extra_diag ) diag_level = 10 ! legacy use of extra_diag
! Store parameter values in the modules data structure
! Note: all rates are provided via input as values per day,
! and are converted here to values per second.
!-- Breakdown and mineralisation (basic pool)
data%Rpoc_hydrol = Rpoc_hydrol/secs_per_day
data%Rpon_hydrol = Rpon_hydrol/secs_per_day
data%Rpop_hydrol = Rpop_hydrol/secs_per_day
data%Rdoc_minerl = Rdoc_minerl/secs_per_day
data%Rdon_minerl = Rdon_minerl/secs_per_day
data%Rdop_minerl = Rdop_minerl/secs_per_day
data%Rdom_minerl = Rdom_minerl/secs_per_day
data%theta_hydrol = theta_hydrol
data%theta_minerl = theta_minerl
data%Kpom_hydrol = Kpom_hydrol
data%Kdom_minerl = Kdom_minerl
data%f_an = f_an
data%simDenitrification = simDenitrification
data%simFeReduction = simFeReduction
data%simSO4Reduction = simSO4Reduction
data%simMethanogenesis = simMethanogenesis
data%K_nit = K_nit
data%Kin_denitrat = Kin_denitrat
data%Kin_denitrit = Kin_denitrit
data%Kin_denitrous = Kin_denitrous
data%Klim_denitrit = Klim_denitrit
data%Klim_denitrous = Klim_denitrous
data%Kpart_denitrit = Kpart_denitrit
!-- Refractory organic matter (optional)
data%simRPools = simRPools
data%Rdomr_minerl = Rdomr_minerl/secs_per_day
data%Rcpom_bdown = Rcpom_bdown/secs_per_day
data%X_cpom_n = X_cpom_n
data%X_cpom_p = X_cpom_p
!-- Light related parameters
data%KeDOM = KeDOM
data%KePOM = KePOM
data%KeDOMR = KeDOMR
data%KeCPOM = KeCPOM
data%simPhotolysis = simPhotolysis
data%photo_fmin = photo_fmin
c = photo_c
!-- Particle settling parameters
data%settling = settling
data%w_pom = w_pom/secs_per_day
data%d_pom = d_pom
data%rho_pom = rho_pom
data%w_cpom = w_cpom/secs_per_day
data%d_cpom = d_cpom
data%rho_cpom = rho_cpom
IF( settling==0 ) THEN
w_pom=zero_; w_cpom=zero_
ENDIF
!-- Sediment interaction parameters (basic model)
data%resuspension = resuspension
data%simSedimentOM = simSedimentOM
data%sedimentOMfrac = sedimentOMfrac
data%Xsc = Xsc
data%Xsn = Xsn
data%Xsp = Xsp
data%Fsed_doc = Fsed_doc/secs_per_day
data%Fsed_don = Fsed_don/secs_per_day
data%Fsed_dop = Fsed_dop/secs_per_day
data%Ksed_dom = Ksed_dom
data%theta_sed_dom = theta_sed_dom
! Register state variables
data%id_doc = aed_define_variable('doc','mmol/m**3','dissolved organic carbon', &
doc_initial,minimum=om_min,maximum=om_max)
data%id_poc = aed_define_variable('poc','mmol/m**3','particulate organic carbon', &
poc_initial,minimum=om_min,maximum=om_max,mobility=data%w_pom)
data%id_don = aed_define_variable('don','mmol/m**3','dissolved organic nitrogen', &
don_initial,minimum=om_min,maximum=om_max)
data%id_pon = aed_define_variable('pon','mmol/m**3','particulate organic nitrogen', &
pon_initial,minimum=om_min,maximum=om_max,mobility=data%w_pom)
data%id_dop = aed_define_variable('dop','mmol/m**3','dissolved organic phosphorus', &
dop_initial,minimum=om_min,maximum=om_max)
data%id_pop = aed_define_variable('pop','mmol/m**3','particulate organic phosphorus', &
pop_initial,minimum=om_min,maximum=om_max,mobility=data%w_pom)
data%id_docr = 0 ; data%id_donr = 0
data%id_dopr = 0 ; data%id_cpom = 0
IF (simRPools) THEN
data%id_docr = aed_define_variable('docr','mmol/m**3',&
'refractory dissolved organic carbon',&
docr_initial,minimum=zero_)
data%id_donr = aed_define_variable('donr','mmol/m**3',&
'refractory dissolved organic nitrogen',&
donr_initial,minimum=zero_)
data%id_dopr = aed_define_variable('dopr','mmol/m**3',&
'refractory dissolved organic phosphorus',&
dopr_initial,minimum=zero_)
data%id_cpom = aed_define_variable('cpom','mmol/m**3',&
'coarse particulate matter',&
cpom_initial,minimum=zero_,mobility=data%w_cpom)
ENDIF
IF (simSedimentOM>0) THEN
! Initialise OM pools here.
! simSedimentOM = 1 - initialise to zero and look at relative evolution
! simSedimentOM = 2 - initialise mass based %OM and bulk density (assume 50:50 POM:DOM)
initial_sedom = zero_
IF (simSedimentOM>1) &
initial_sedom = sedimentBulkDens * sedimentDepth * sedimentOMfrac * Xsc * 0.5 / (12.0/1e3)
data%id_sed_doc = aed_define_sheet_variable( 'sed_doc', &
'mmol/m**2', &
'sediment doc mass', &
initial_sedom, &
minimum=-1e10)
IF (simSedimentOM>1) &
initial_sedom = sedimentBulkDens * sedimentDepth * sedimentOMfrac * Xsn * 0.5 / (14.0/1e3)
data%id_sed_don = aed_define_sheet_variable( 'sed_don', &
'mmol/m**2', &
'sediment don mass', &
initial_sedom, &
minimum=-1e10)
IF (simSedimentOM>1) &
initial_sedom = sedimentBulkDens * sedimentDepth * sedimentOMfrac * Xsp * 0.5 / (30.9/1e3)
data%id_sed_dop = aed_define_sheet_variable( 'sed_dop', &
'mmol/m**2', &
'sediment dop mass', &
initial_sedom, &
minimum=-1e10)
IF (simSedimentOM>1) &
initial_sedom = sedimentBulkDens * sedimentDepth * sedimentOMfrac * Xsc * 0.5 / (12.0/1e3)
data%id_sed_poc = aed_define_sheet_variable( 'sed_poc', &
'mmol/m**2', &
'sediment poc mass', &
initial_sedom, &
minimum=-1e10)
IF (simSedimentOM>1) &
initial_sedom = sedimentBulkDens * sedimentDepth * sedimentOMfrac * Xsn * 0.5 / (14.0/1e3)
data%id_sed_pon = aed_define_sheet_variable( 'sed_pon', &
'mmol/m**2', &
'sediment pon mass', &
initial_sedom, &
minimum=-1e10)
IF (simSedimentOM>1) &
initial_sedom = sedimentBulkDens * sedimentDepth * sedimentOMfrac * Xsp * 0.5 / (30.9/1e3)
data%id_sed_pop = aed_define_sheet_variable( 'sed_pop', &
'mmol/m**2', &
'sediment pop mass', &
initial_sedom, &
minimum=-1e10)
ENDIF
! Register external (linked) state variable dependencies
!-- oxygen & oxidants
data%use_nit = .FALSE. ; data%use_no2 = .FALSE. ; data%use_n2o = .FALSE.
data%use_oxy = dom_miner_oxy_reactant_var .NE. '' !This means oxygen module switched on
IF (data%use_oxy) &
data%id_oxy = aed_locate_variable(dom_miner_oxy_reactant_var)
IF( simDenitrification==1 ) THEN
data%use_nit = dom_miner_nit_reactant_var .NE. ''
IF (data%use_nit) THEN
data%id_nit = aed_locate_variable(dom_miner_nit_reactant_var)
ENDIF
ELSEIF( simDenitrification==2 ) THEN
data%use_nit = dom_miner_nit_reactant_var .NE. ''
IF (data%use_nit) data%id_nit = aed_locate_variable(dom_miner_nit_reactant_var)
data%use_no2 = dom_miner_no2_reactant_var .NE. ''
IF (data%use_no2) data%id_no2 = aed_locate_variable(dom_miner_no2_reactant_var)
data%use_n2o = dom_miner_n2o_reactant_var .NE. ''
IF (data%use_n2o) data%id_n2o = aed_locate_variable(dom_miner_n2o_reactant_var)
ENDIF
IF( simFeReduction==1 ) THEN
data%use_fe3 = dom_miner_fe3_reactant_var .NE. ''
IF (data%use_fe3) THEN
data%id_fe = aed_locate_variable(dom_miner_fe3_reactant_var)
ELSE
simFeReduction = 0
ENDIF
ELSE
data%use_fe3 = .FALSE.
ENDIF
IF( simSO4Reduction==1 ) THEN
data%use_so4 = dom_miner_so4_reactant_var .NE. ''
IF (data%use_so4) THEN
data%id_so4 = aed_locate_variable(dom_miner_so4_reactant_var)
ELSE
simSO4Reduction = 0
ENDIF
ELSE
data%use_so4 = .FALSE.
ENDIF
IF( simMethanogenesis==1 ) THEN
data%use_ch4 = dom_miner_ch4_reactant_var .NE. ''
IF (data%use_ch4) THEN
data%id_ch4 = aed_locate_variable(dom_miner_ch4_reactant_var)
ELSE
simMethanogenesis = 0
ENDIF
ELSE
data%use_ch4 = .FALSE.
ENDIF
!-- carbon
data%use_dic = doc_miner_product_variable .NE. '' !This means carbon module switched on
IF (data%use_dic) &
data%id_dic = aed_locate_variable(doc_miner_product_variable)
!-- nitrogen
data%use_amm = don_miner_product_variable .NE. '' !This means nitrogen module switched on
IF (data%use_amm) &
data%id_amm = aed_locate_variable(don_miner_product_variable)
!-- phosphorus
data%use_frp = dop_miner_product_variable .NE. '' !This means phosphorus module switched on
IF (data%use_frp) &
data%id_frp = aed_locate_variable(dop_miner_product_variable)
!-- sediment flux link variables
data%id_Fsed_pon = -1 ; data%id_Fsed_pop = -1 ; data%id_Fsed_poc = -1
data%id_Fsed_don = -1 ; data%id_Fsed_dop = -1 ; data%id_Fsed_doc = -1
data%use_Fsed_link_doc = Fsed_doc_variable .NE. ''
IF (data%use_Fsed_link_doc) data%id_Fsed_doc = aed_locate_sheet_variable(Fsed_doc_variable)
data%use_Fsed_link_don = Fsed_don_variable .NE. ''
IF (data%use_Fsed_link_don) data%id_Fsed_don = aed_locate_sheet_variable(Fsed_don_variable)
data%use_Fsed_link_dop = Fsed_dop_variable .NE. ''
IF (data%use_Fsed_link_dop) data%id_Fsed_dop = aed_locate_sheet_variable(Fsed_dop_variable)
data%use_Fsed_link_poc = Fsed_poc_variable .NE. ''
IF (data%use_Fsed_link_poc) data%id_Fsed_poc = aed_locate_sheet_variable(Fsed_poc_variable)
data%use_Fsed_link_pon = Fsed_pon_variable .NE. ''
IF (data%use_Fsed_link_pon) data%id_Fsed_pon = aed_locate_sheet_variable(Fsed_pon_variable)
data%use_Fsed_link_pop = Fsed_pop_variable .NE. ''
IF (data%use_Fsed_link_pop) data%id_Fsed_pop = aed_locate_sheet_variable(Fsed_pop_variable)
!-- sedimentation link variables
data%id_Psed_poc = -1 ; data%id_Psed_pon = -1 ; data%id_Psed_pop = -1
data%use_Psed_link_poc = Psed_poc_variable .NE. ''
IF (data%use_Psed_link_poc) THEN
data%id_Psed_poc = aed_locate_sheet_variable(Psed_poc_variable)
ELSE
data%id_Psed_poc = aed_define_diag_variable('Psed_poc','mmol/m**2/s', 'POC sedimentation')
IF (simRPools) &
data%id_Psed_cpom = aed_define_diag_variable('Psed_cpom','mmol/m**2/s', 'CPOM sedimentation')
ENDIF
data%use_Psed_link_pon = Psed_pon_variable .NE. ''
IF (data%use_Psed_link_pon) THEN
data%id_Psed_pon = aed_locate_sheet_variable(Psed_pon_variable)
ELSE
data%id_Psed_pon = aed_define_diag_variable('Psed_pon','mmol/m**2/s', 'PON sedimentation')
ENDIF
IF (data%use_Psed_link_pop) THEN
data%id_Psed_pop = aed_locate_sheet_variable(Psed_pop_variable)
ELSE
data%id_Psed_pop = aed_define_diag_variable('Psed_pop','mmol/m**2/s', 'POP sedimentation')
ENDIF
!-- resuspension link variable
IF ( resuspension>0 .AND. .NOT.resus_link .EQ. '' ) THEN
data%id_l_resus = aed_locate_sheet_variable(TRIM(resus_link)) ! ('TRC_resus')
ELSE
data%id_l_resus = 0
data%resuspension = 0
ENDIF
!-- light
IF (simRPools) THEN
data%id_vis = aed_locate_global('par')
data%id_uva = aed_locate_global('uva')
data%id_uvb = aed_locate_global('uvb')
data%id_extc= aed_locate_global('extc_coef')
data%id_dz = aed_locate_global('layer_ht')
ENDIF
! Register diagnostic variables
data%id_swi_poc = 0
data%id_swi_doc = 0
data%id_swi_pon = 0
data%id_swi_don = 0
data%id_swi_pop = 0
data%id_swi_dop = 0
data%id_poc_miner = 0
data%id_doc_miner = 0
data%id_pon_miner = 0
data%id_don_miner = 0
data%id_pop_miner = 0
data%id_dop_miner = 0
data%id_denit = 0
data%id_bod = 0
data%id_photolysis = 0
data%id_docr_miner = 0
data%id_donr_miner = 0
data%id_dopr_miner = 0
IF ( diag_level>0 ) THEN
data%id_cdom = aed_define_diag_variable('CDOM','/m', 'Chromophoric DOM (CDOM)')
data%id_sed_toc = aed_define_sheet_diag_variable('sed_toc','mmol/m**2', 'Sediment TOC mass')
data%id_sed_ton = aed_define_sheet_diag_variable('sed_ton','mmol/m**2', 'Sediment TON mass')
data%id_sed_top = aed_define_sheet_diag_variable('sed_top','mmol/m**2', 'Sediment TOP mass')
ENDIF
IF ( diag_level>1 ) THEN
data%id_swi_poc = aed_define_sheet_diag_variable('swi_poc','mmol/m**2/d', 'Net POC flux @ the SWI')
data%id_swi_doc = aed_define_sheet_diag_variable('swi_doc','mmol/m**2/d', 'Net DOC flux @ the SWI')
data%id_swi_pon = aed_define_sheet_diag_variable('swi_pon','mmol/m**2/d', 'Net PON flux @ the SWI')
data%id_swi_don = aed_define_sheet_diag_variable('swi_don','mmol/m**2/d', 'Net DON flux @ the SWI')
data%id_swi_pop = aed_define_sheet_diag_variable('swi_pop','mmol/m**2/d', 'Net POP flux @ the SWI')
data%id_swi_dop = aed_define_sheet_diag_variable('swi_dop','mmol/m**2/d', 'Net DOP flux @ the SWI')
data%id_poc_miner= aed_define_diag_variable('poc_hydrol','mmol/m**3/d','POC hydrolosis')
data%id_doc_miner= aed_define_diag_variable('doc_miner' ,'mmol/m**3/d','DOC mineralisation')
data%id_pon_miner= aed_define_diag_variable('pon_hydrol','mmol/m**3/d','PON hydrolosis')
data%id_don_miner= aed_define_diag_variable('don_miner' ,'mmol/m**3/d','DON mineralisation')
data%id_pop_miner= aed_define_diag_variable('pop_hydrol','mmol/m**3/d','POP hydrolysis')
data%id_dop_miner= aed_define_diag_variable('dop_miner' ,'mmol/m**3/d','DOP mineralisation')
data%id_anaerobic= aed_define_diag_variable('anaerobic' ,'mmol/m**3/d','anaerobic metabolism')
data%id_denit = aed_define_diag_variable('denit' ,'mmol/m**3/d','denitrification')
IF (simRPools) THEN
data%id_docr_miner = aed_define_diag_variable('docr_miner','mmol/m**3/d','DOCR mineralisation')
data%id_donr_miner = aed_define_diag_variable('donr_miner','mmol/m**3/d','DONR mineralisation')
data%id_dopr_miner = aed_define_diag_variable('dopr_miner','mmol/m**3/d','DOPR mineralisation')
ENDIF
data%id_bod = aed_define_diag_variable('BOD5','mg O2/L', 'Biochemical Oxygen Demand (BOD)')
IF ( simPhotolysis .and. simRpools ) data%id_photolysis = &
aed_define_diag_variable('photolysis','mmol C/m3/d', 'photolysis rate of breakdown of DOC')
data%id_pom_vvel = aed_define_diag_variable('pom_vvel','m/d','POM vertical velocity')
data%id_cpom_vvel = aed_define_diag_variable('cpom_vvel','m/d','CPOM vertical velocity')
ENDIF
! Register environmental dependencies
data%id_temp = aed_locate_global('temperature')
data%id_salt = aed_locate_global('salinity')
data%id_rho = aed_locate_global('density')
END SUBROUTINE aed_define_organic_matter
!+++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
!###############################################################################
SUBROUTINE aed_calculate_organic_matter(data,column,layer_idx)
!-------------------------------------------------------------------------------
! Right hand sides of aed_organic_matter model
!-------------------------------------------------------------------------------
!ARGUMENTS
CLASS (aed_organic_matter_data_t),INTENT(in) :: data
TYPE (aed_column_t),INTENT(inout) :: column(:)
INTEGER,INTENT(in) :: layer_idx
!
!LOCALS
AED_REAL :: poc,pon,pop
AED_REAL :: doc,don,dop
AED_REAL :: docr,donr,dopr,cpom,cdom
AED_REAL :: temp,dic,amm,oxy,nit,no2,n2o,frp,feiii,so4,ch4
AED_REAL :: pom_hydrolysis, dom_mineralisation
AED_REAL :: pon_hydrolysis, don_mineralisation
AED_REAL :: pop_hydrolysis, dop_mineralisation
AED_REAL :: poc_hydrolysis, doc_mineralisation
AED_REAL :: docr_mineralisation = 0., donr_mineralisation = 0.
AED_REAL :: dopr_mineralisation = 0., cpom_breakdown = 0.
AED_REAL :: denitrification, denitratation = 0., denitritation = 0.
AED_REAL :: denitrousation = 0., dnra, nitrous_denitritation, ammonium_release
AED_REAL :: photolysis, vis, uva, uvb, photo_fmin, cdoc, att
AED_REAL :: doc_min_aerobic, doc_min_anaerobic
AED_REAL :: fereduction = 0., so4reduction = 0., methanogenesis = 0., fso4, fnit, ffe
!-----------------------------------------------------------------------
!BEGIN
!CALL log_message('model aed_organic_matter enter do loop successfully.')
!---------------------------------------------------------------------------+
!# Setup
!---------------------------------------------------------------------------+
!# Initialisations
nit = zero_
docr = zero_
photolysis = zero_
denitrification = zero_
photo_fmin = data%photo_fmin
!# Retrieve current environmental conditions.
temp = _STATE_VAR_(data%id_temp) ! temperature
!# Retrieve current (local) state variable values.
poc = _STATE_VAR_(data%id_poc) ! particulate organic carbon
pon = _STATE_VAR_(data%id_pon) ! particulate organic nitrogen
pop = _STATE_VAR_(data%id_pop) ! particulate organic phosphorus
doc = _STATE_VAR_(data%id_doc) ! dissolved organic carbon
don = _STATE_VAR_(data%id_don) ! dissolved organic nitrogen
dop = _STATE_VAR_(data%id_dop) ! dissolved organic phosphorus
IF(data%simRPools) THEN
docr = _STATE_VAR_(data%id_docr)
donr = _STATE_VAR_(data%id_donr)
dopr = _STATE_VAR_(data%id_dopr)
cpom = _STATE_VAR_(data%id_cpom)
att = EXP( -_STATE_VAR_(data%id_extc) * _STATE_VAR_(data%id_dz)/2. )
vis = _STATE_VAR_(data%id_vis) * att
uva = _STATE_VAR_(data%id_uva) * att
uvb = _STATE_VAR_(data%id_uvb) * att
cdom = _DIAG_VAR_(data%id_cdom)
ENDIF
! IF (data%id_n_den>0) denitrification = _DIAG_VAR_(data%id_n_den) / secs_per_day
IF (data%id_denit>0) denitrification = _DIAG_VAR_(data%id_denit) / secs_per_day
IF (data%use_oxy) THEN
oxy = _STATE_VAR_(data%id_oxy) ! oxygen
ELSE
oxy = 300.0
ENDIF
IF (data%use_nit) THEN
nit = _STATE_VAR_(data%id_nit) ! nitrate
ELSE
nit = 300.0
ENDIF
IF (data%use_no2) THEN
no2 = _STATE_VAR_(data%id_no2) ! nitrite
ELSE
no2 = 300.0
ENDIF
IF (data%use_n2o) THEN
n2o = _STATE_VAR_(data%id_n2o) ! nitrous oxide
ELSE
n2o = 300.0
ENDIF
IF (data%use_dic) THEN
dic = _STATE_VAR_(data%id_dic) ! dissolved inorganic carbon
ENDIF
IF (data%use_amm) THEN
amm = _STATE_VAR_(data%id_amm) ! ammonium
ENDIF
IF (data%use_frp) THEN
frp = _STATE_VAR_(data%id_frp) ! phosphate
ENDIF
IF (data%use_fe3) THEN
feiii = _STATE_VAR_(data%id_fe)
ELSE
feiii = 0.
ENDIF
IF (data%use_so4) THEN
so4 = _STATE_VAR_(data%id_so4)
ELSE
so4 = 100.
ENDIF
IF (data%use_ch4) THEN
ch4 = _STATE_VAR_(data%id_ch4)
ELSE
ch4 = 0.
ENDIF
!---------------------------------------------------------------------------+
!# Reaction rates
!---------------------------------------------------------------------------+
! Compute hydroloysis and mineralisation (units mmol N/m3/day)
poc_hydrolysis = poc*fpoc_miner(data%use_oxy,data%Rpoc_hydrol,data%Kpom_hydrol,data%theta_hydrol,oxy,temp)
pon_hydrolysis = pon*fpon_miner(data%use_oxy,data%Rpon_hydrol,data%Kpom_hydrol,data%theta_hydrol,oxy,temp)
pop_hydrolysis = pop*fpop_miner(data%use_oxy,data%Rpop_hydrol,data%Kpom_hydrol,data%theta_hydrol,oxy,temp)
dom_mineralisation = R_dom(data%Rdom_minerl,data%Kdom_minerl,data%f_an,data%theta_minerl,oxy,temp)
doc_mineralisation = doc*dom_mineralisation
don_mineralisation = don*dom_mineralisation
dop_mineralisation = dop*dom_mineralisation
!doc_mineralisation = fdoc_miner(data%use_oxy,data%Rdoc_minerl,data%Kdom_minerl,data%theta_minerl,oxy,temp)
!don_mineralisation = fdon_miner(data%use_oxy,data%Rdon_minerl,data%Kdom_minerl,data%theta_minerl,oxy,temp)
!dop_mineralisation = fdop_miner(data%use_oxy,data%Rdop_minerl,data%Kdom_minerl,data%theta_minerl,oxy,temp)
IF (data%simRPools) THEN
cpom_breakdown = cpom*fpoc_miner(data%use_oxy,data%Rcpom_bdown,data%Kpom_hydrol,data%theta_hydrol,oxy,temp)
dom_mineralisation = R_dom(data%Rdomr_minerl,data%Kdom_minerl,data%f_an,data%theta_minerl,oxy,temp)
docr_mineralisation = docr*dom_mineralisation
donr_mineralisation = donr*dom_mineralisation
dopr_mineralisation = dopr*dom_mineralisation
!docr_mineralisation = fdoc_miner(data%use_oxy,data%Rdocr_miner,data%Kdom_minerl,data%theta_minerl,oxy,temp)
!donr_mineralisation = fdoc_miner(data%use_oxy,data%Rdonr_miner,data%Kdom_minerl,data%theta_minerl,oxy,temp)
!dopr_mineralisation = fdoc_miner(data%use_oxy,data%Rdopr_miner,data%Kdom_minerl,data%theta_minerl,oxy,temp)
IF ( data%simPhotolysis ) THEN
photolysis = photo(vis,cdom,1) + photo(uva,cdom,2) + photo(uvb,cdom,3)
!# Limit photolysis to 90% of doc pool within 1 hour
IF(photolysis > 0.9*docr/3.6e3) photolysis = 0.9*docr/3.6e3
ENDIF
ENDIF
!---------------------------------------------------------------------------+
!# Flux updates for the ODE
!---------------------------------------------------------------------------+
!---------------------------------------------------------------------------+
! Set temporal derivatives : POM breakdown
_FLUX_VAR_(data%id_poc) = _FLUX_VAR_(data%id_poc) - poc_hydrolysis
_FLUX_VAR_(data%id_pon) = _FLUX_VAR_(data%id_pon) - pon_hydrolysis
_FLUX_VAR_(data%id_pop) = _FLUX_VAR_(data%id_pop) - pop_hydrolysis
!---------------------------------------------------------------------------+
! Set temporal derivatives : DOM metabolism
_FLUX_VAR_(data%id_doc) = _FLUX_VAR_(data%id_doc) + poc_hydrolysis - doc_mineralisation
_FLUX_VAR_(data%id_don) = _FLUX_VAR_(data%id_don) + pon_hydrolysis - don_mineralisation
_FLUX_VAR_(data%id_dop) = _FLUX_VAR_(data%id_dop) + pop_hydrolysis - dop_mineralisation
!---------------------------------------------------------------------------+
! Set temporal derivatives : Refractory Pools
IF (data%simRPools) THEN
docr = MAX(1.e-3,docr)
_FLUX_VAR_(data%id_docr) = _FLUX_VAR_(data%id_docr) - docr_mineralisation - photolysis
_FLUX_VAR_(data%id_doc) = _FLUX_VAR_(data%id_doc) + &
docr_mineralisation + photolysis*photo_fmin
_FLUX_VAR_(data%id_donr) = _FLUX_VAR_(data%id_donr) - &
donr_mineralisation - photolysis*(donr/docr)
_FLUX_VAR_(data%id_don) = _FLUX_VAR_(data%id_don) + &
donr_mineralisation + photolysis*photo_fmin*(donr/docr)
_FLUX_VAR_(data%id_dopr) = _FLUX_VAR_(data%id_dopr) - &
dopr_mineralisation - photolysis*(dopr/docr)
_FLUX_VAR_(data%id_dop) = _FLUX_VAR_(data%id_dop) + &
dopr_mineralisation + photolysis*photo_fmin*(dopr/docr)
_FLUX_VAR_(data%id_cpom) = _FLUX_VAR_(data%id_cpom) - cpom_breakdown
_FLUX_VAR_(data%id_poc) = _FLUX_VAR_(data%id_poc) + (cpom_breakdown)
_FLUX_VAR_(data%id_pon) = _FLUX_VAR_(data%id_pon) + (cpom_breakdown)*data%X_cpom_n
_FLUX_VAR_(data%id_pop) = _FLUX_VAR_(data%id_pop) + (cpom_breakdown)*data%X_cpom_p
ENDIF
!---------------------------------------------------------------------------+
!# Set temporal derivatives : OXIDANTS
doc_min_aerobic = doc_mineralisation * (oxy/(data%Kdom_minerl+oxy))
doc_min_anaerobic = doc_mineralisation - doc_min_aerobic
fnit = one_; ffe = one_; fso4 = one_
IF (data%use_oxy) THEN
!# Aerobic mineralisation : O2 consumption
_FLUX_VAR_(data%id_oxy) = _FLUX_VAR_(data%id_oxy) - doc_min_aerobic
ENDIF
IF( data%simDenitrification==1 ) THEN
!# De-nitrification : simple denitrification, using NO3
denitrification = doc_min_anaerobic * nit/(data%K_nit+nit)
_FLUX_VAR_(data%id_nit) = _FLUX_VAR_(data%id_nit) - denitrification
fnit = data%K_nit/(data%K_nit+nit)
ELSEIF( data%simDenitrification==2 ) THEN
!# De-nitrification : complex model involving NO2, NO3, N2O
! We 1st partition metabolism across the pathways to N2:
! Denitratation (1st step in denitrification: NO3->NO2)
! Denitritation (2nd step in denitrification: NO2->N2O&NH4)
! Denitrousation (Last step in denitrification: N2O->N2)
denitratation = (doc_mineralisation) * nit/(data%K_nit+nit) * data%Kin_denitrat/(data%Kin_denitrat+oxy) * &
data%Klim_denitrous/(data%Klim_denitrous +n2o) * data%Klim_denitrit/(data%Klim_denitrit +no2)
denitritation = (doc_mineralisation) * no2/(data%Klim_denitrit + no2) * data%Kin_denitrit/(data%Kin_denitrit+oxy) * &
data%Klim_denitrous/(data%Klim_denitrous + n2o)
denitrousation = (doc_mineralisation) * n2o/(data%Klim_denitrous+n2o) * data%Kin_denitrous/(data%Kin_denitrous+oxy)
!# Check the denitrified DOM is not more than the total anaerobic allowed
denitrification = denitratation+denitritation+denitrousation
IF ( denitrification > doc_min_anaerobic ) THEN
denitratation = denitratation * doc_min_anaerobic/denitrification
denitritation = denitritation * doc_min_anaerobic/denitrification
denitrousation = denitrousation * doc_min_anaerobic/denitrification
ENDIF
dnra = denitritation * data%Kpart_denitrit/(data%Kpart_denitrit+no2)
nitrous_denitritation = denitritation * no2/(data%Kpart_denitrit+no2) * 0.5
ammonium_release = (denitratation + denitritation + denitrousation) * MIN(don/MAX(doc,1e-2),one_) ! data%X_nc
_FLUX_VAR_(data%id_nit) = _FLUX_VAR_(data%id_nit) - denitratation
_FLUX_VAR_(data%id_no2) = _FLUX_VAR_(data%id_no2) + denitratation - denitritation
_FLUX_VAR_(data%id_n2o) = _FLUX_VAR_(data%id_n2o) + nitrous_denitritation - denitrousation
_FLUX_VAR_(data%id_amm) = _FLUX_VAR_(data%id_amm) + dnra + ammonium_release
fnit = data%K_nit/(data%K_nit+(nit+no2))
ENDIF
doc_min_anaerobic = doc_min_anaerobic - denitrification
IF( data%simFeReduction>0 ) THEN
!# Iron reduction : anaerobic breakdown, after denitrification etc
fereduction = doc_min_anaerobic * feiii/(data%K_fe+feiii) * fnit
ffe = data%K_fe/(data%K_fe+feiii)
_FLUX_VAR_(data%id_fe) = _FLUX_VAR_(data%id_fe) - fereduction ! stoich
ENDIF
doc_min_anaerobic = doc_min_anaerobic - fereduction
IF( data%simSO4Reduction>0 ) THEN
!# Sulfate reduction : anaerobic breakdown, after denitrification etc
so4reduction = doc_min_anaerobic * so4/(data%K_so4+so4) * ffe * fnit
fso4 = so4/(data%K_so4+so4)
_FLUX_VAR_(data%id_so4) = _FLUX_VAR_(data%id_so4) - so4reduction ! stoich
ENDIF
doc_min_anaerobic = doc_min_anaerobic - so4reduction
IF( data%simMethanogenesis>0 ) THEN
!# Methanogenesis : anaerobic breakdown, after all other pathways
methanogenesis = doc_min_anaerobic * fso4 * ffe * fnit
_FLUX_VAR_(data%id_ch4) = _FLUX_VAR_(data%id_ch4) - methanogenesis ! stoich
ENDIF
doc_min_anaerobic = doc_min_anaerobic - methanogenesis
!---------------------------------------------------------------------------+
! Set temporal derivatives : PRODUCTS of mineralisation
if (data%use_dic) THEN
_FLUX_VAR_(data%id_dic) = _FLUX_VAR_(data%id_dic) + (doc_mineralisation)
IF ( data%simRPools ) _FLUX_VAR_(data%id_dic) = &
_FLUX_VAR_(data%id_dic) + photolysis*(1.-photo_fmin)
ENDIF
IF (data%use_amm) THEN
IF( data%simDenitrification==1 ) &
_FLUX_VAR_(data%id_amm) = _FLUX_VAR_(data%id_amm) + (don_mineralisation)
!IF( data%simDenitrification==2 ) & !MH needs balacing with Denit fraction
! _FLUX_VAR_(data%id_amm) = _FLUX_VAR_(data%id_amm) + (don_mineralisation)
IF ( data%simRPools ) &
_FLUX_VAR_(data%id_amm) = _FLUX_VAR_(data%id_amm) + &
photolysis*(1.-photo_fmin)*MIN(donr/MAX(docr,1e-2),one_)
ENDIF
IF (data%use_frp) THEN
_FLUX_VAR_(data%id_frp) = _FLUX_VAR_(data%id_frp) + (dop_mineralisation)
IF ( data%simRPools ) &
_FLUX_VAR_(data%id_frp) = _FLUX_VAR_(data%id_frp) + photolysis*(1.-photo_fmin)*(dopr/docr)
ENDIF
!---------------------------------------------------------------------------+
!# Export diagnostic variables
!---------------------------------------------------------------------------+
!-- CDOM computed as a function of DOC amount, as empirically defined by
! Kostoglidis et al 2005 for Swan-Canning
IF ( diag_level>0 ) THEN
IF ( data%simRPools ) THEN
cdoc = MIN(doc+docr,1.e4)
ELSE
cdoc = MIN(doc,1.e4)
ENDIF
_DIAG_VAR_(data%id_cdom) = 0.35*exp(0.1922*(cdoc)*(12./1e3))
ENDIF
!-- Extra diagnostics
IF ( diag_level>1 ) THEN
! General breakdown rates
_DIAG_VAR_(data%id_poc_miner) = poc_hydrolysis*secs_per_day
_DIAG_VAR_(data%id_pon_miner) = pon_hydrolysis*secs_per_day
_DIAG_VAR_(data%id_pop_miner) = pop_hydrolysis*secs_per_day
_DIAG_VAR_(data%id_doc_miner) = doc_mineralisation*secs_per_day
_DIAG_VAR_(data%id_don_miner) = don_mineralisation*secs_per_day
_DIAG_VAR_(data%id_dop_miner) = dop_mineralisation*secs_per_day
IF ( data%simRPools ) THEN
_DIAG_VAR_(data%id_docr_miner) = docr_mineralisation*secs_per_day
_DIAG_VAR_(data%id_donr_miner) = donr_mineralisation*secs_per_day
_DIAG_VAR_(data%id_dopr_miner) = dopr_mineralisation*secs_per_day
ENDIF
! BOD5 is computed as the amount of oxygen consumed over a 5-day period (mgO2/L)
_DIAG_VAR_(data%id_bod) = 32./12.*(doc_mineralisation*secs_per_day*12./1e3)*5.0
IF ( data%simPhotolysis ) &
_DIAG_VAR_(data%id_photolysis) = photolysis*secs_per_day
! Anaerobic OM mineralisation
_DIAG_VAR_(data%id_denit) = denitrification*secs_per_day
_DIAG_VAR_(data%id_anaerobic) = doc_min_anaerobic*secs_per_day
IF ( data%simDenitrification>1 ) &
_DIAG_VAR_(data%id_denit) = denitratation + denitritation + denitrousation
ENDIF
END SUBROUTINE aed_calculate_organic_matter
!+++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++++
!###############################################################################
SUBROUTINE aed_calculate_benthic_organic_matter(data,column,layer_idx)
!-------------------------------------------------------------------------------
! Calculate pelagic bottom fluxes and benthic sink / source terms of AED OGM.
! Everything here is in units per surface area (not volume!) per time.
!-------------------------------------------------------------------------------
!ARGUMENTS