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Atomic Data

James Matthews edited this page Jul 30, 2013 · 7 revisions

This is currently the old page. Will be updated in due course.

This is a description of how to get and use atomic data for Python ksl's earlier work on this is on confluence. The principle motivation for this page is to understand how to add macro atoms

Location of information

  • NIST: Claims and probably is the best, but the data are not organized as well as in other databases. Thus NIST requires more hand work
  • Chianti: contains everything one needs, except photoionzation, but is not as complete as NIST.
    • The files presented are all ascii, and the columns are defined int he Chianti users guide
    • The basic files for use in python for each ion are .elvlc - the energy level file, the wgfa file - the lines file with oscillator strengths. There are also other files, especially one for collision strengths which might be useful in future
  • Topbase: The general problem with topbase is the accuracy of the wavelengths that are reported. (There is an associated TipBase ? but as far as ksl could determine this was not exceptionally helpful)

MacroAtoms

Basically to add MacroAtoms one needs to do the following: Modify the ion information to allow for treating a particular ion as a MacroAtom, basically setting aside storage for the MacroAtom ? Add level information in a special format Add line information in a special format Add photoionziation data in a special format The crucial bits in this assure that one has the correct linkages between lines and levels and photoionization. At present, an atom needs to be treated as either a simple atom or a MacroAtom. One cannot mix simple and MacroIons of the same atom. This is a limitation of the code and if necessary could be changed.

Ions
Normal Ion records look like this
IonV    H   1   1   2   13.59900 1000   5     1s(2S_{1/2})
IonV    H   1   2   2 1.0000e+20   0   0     Bare
Ion Macro records look like this
IonM    H   1   1   2   13.59900   20  20     1s(2S_{1/2})
IonM    H   1   2   1 1.0000e+20    1   1     Bare

There is no obvious difference between the ! IonM ? records and the IonV records. Both set aside room for a maximum number of levels, and then a number of levels to be treated differently. In practice an ion probably needs to be treated as a MacroIon or not in the code. One cannot mix within a single run of the code. The extra levels in the IonV were probably the result of an abortive initial attempt at detailed balance that predated the MacroAtom approach.

Levels

# Maximum excitation above ground (in Ryd)  for inclusion  4.000000
# Miniumum excitation below continuum (in Ryd) for inclusion -0.100000
# Topbase levels: Order changed to move config to end of line
#LevTop  z ion  iSLP iLV iCONF   E(eV) Te(eV) gi RL(s) eqn RL(s)
# ======================================================================================
#      i NZ NE iSLP iLV iCONF                 E(RYD)      TE(RYD)   gi     EQN    RL(NS)
# ======================================================================================
# ======================================================================================
LevTop  1  1  200  1 -13.605698   0.000000  2  1.0000 1.00e+21 () 1s
LevTop  1  1  200  2  -3.401425  10.204273  2  2.0000 1.00e+21 () 2s
LevTop  1  1  211  1  -3.401425  10.204273  6  2.0000 1.60e-09 () 2p
whereas the for Macro Atoms we have
#         z ion lvl ion_pot   ex_energy   g  rad_rate
LevMacro  1  1  1 -13.59843    0.000000   2  1.00e+21 () n=1
LevMacro  1  1  2  -3.39960    10.19883   8  1.00e-09 () n=2
LevMacro  1  1  3  -1.51093    12.08750  18  1.00e-09 () n=3

The columns are exactly the same in both cases. Each Level is described by an element number and ion number and a level number. However there are some specific differences. In particular, for LevTop levels, the excitation energy needs need to be on an absolute scale between ions, and so it includes the ionization energy of the lower level ionization states. Note that the radiative rates are not used. The original intention was to use this to define the difference between metastable and normal levels, with the expectation that if the level was metastable it would be put in Boltzmann equililbrium with the groundstate. Right now python uses 10**15 seconds, essentially a Hubble time to do this, but this portion of the code is not, according to ss, tested. The primary source for this is usually the NIST database, although similar information is usually available in Chianti . One normally wants text output, and eV to describe the levels, and then one needs to put things in energy order. Since they quote J, one converts to g = 2J+1

Lines

For lines, we did not create a specific topbase format, but most of the recent sets of data use a format that is similar to what is need for macro atoms.

Line  1  1  926.226013  0.003184   2   4     0.000000    13.387685    0    9
Line  1  1  930.747986  0.004819   2   4     0.000000    13.322634    0    8
Line  1  1  937.802979  0.007798   2   4     0.000000    13.222406    0    7
Line  1  1  949.742981  0.013931   2   4     0.000000    13.056183    0    6

and for MacroAtoms

# z = element, ion= ionstage, f = osc. str., gl(gu) = stat. we. lower(upper) level
# el(eu) = energy lower(upper) level (eV), ll(lu) = lvl index lower(upper) level
#        z ion       lambda      f         gl  gu    el          eu        ll   lu
LinMacro    1   1          1215.33907             0.41620     2     8             0.00000            10.19883     1     2
LinMacro    1   1          1025.44253             0.07910     2    18             0.00000            12.08750     1     3
LinMacro    1   1           972.27104             0.02899     2    32             0.00000            12.74854     1     4

For LinMacro the columns are an identifier, the element z, the ion number, the wavelength of the line in A, the absoprion oscillator strength, the lower and upper level mulitplicities, the energy of the lower level and upper level. The utlimate source for this information is usually NIST . The main issue with all of this is that one needs to index everything self-consistently. http://physics.nist.gov/PhysRefData/ASD/index.html

Photoionization

and the topbase photoionization records look like

PhotTopS  1  1 200    1    13.605698  50
PhotTop    13.605698 6.304e-18
PhotTop    16.627193 3.679e-18
wheeas the Macro Atoms look like
PhotMacS       1       1       1       1       13.598430     100
PhotMac       13.598430   6.3039999e-18
PhotMac       13.942675   5.8969998e-18

The meaning of the columns is the same in both cases here. It may be simply a historical accident that we have both formats, or probably we were worried we would need to change. Topbase is generally the source for this information.

Atomic Data Collections

In December 2012, NSH was drowning somewhat in different data sets - modfiied and added to over the previous two years in a rather haphazard way. The zipfiles below are his attempt to make a historical record of what data was used at various stages, and to try to set a stake in the ground for what to use. These files are 'self contained' that is the standardXX file points into the directory in which the data expands. The intention is that the directory goes into the atomic directory, a link to which is created when you type execute the script Setup_Py_Dir. The line in the .pf file would then look like Atomic_data atomic/atomicXX/standardXX

atomic_h20- z.atomic_h20.tar.gz - SS Macro atom data This is the macro atom atomic data for the 20 level Hydrogen atom Note: Include ONLY Hydrogen Used for SS's YSO macro atom models Format currently atomic/atomic_h20/h20 Will be used as the base for future macro atom data sets- JM is testing data sets including Hydrogen read in as a macro atom with the other elements treated as 'simple ions'

atomic39 - z.atomic39.121218.tar.gz - Historical This is the data that comes with the full installation here: http://www-int.stsci.edu/~long/xpub/Python/

atomic39_REG - z.atomic39_REG.121218.tar.gz - NSH This is the version of standard39 that NSH used for his regression testing. Changes are elem_ions_ver.py : For some reason (lost to me now) the number of elements included in the elem_ions_ver.py file was reduced from 20 to 14. Basically all element with an abundance less than 1e-6 that of Hydrogen were commented out. Unfortunately (perhaps) this change stuck. recomb.data : In the original data, many lines were commented out. NSH uncommented all of them, since memory is not an issue, it seemed safer to have all data read in, wether it is needed or not. I think I did this because the code was complaining at some point that recomb data was not available for some elements I turned on. This data is now (py74) only a stopgap since the latest data allows the recombination to ground state to be computed from basic data.

atomic70 - z.atomic70.121218.tar.gz - NSH This is almost identical to standard39_REG, but with a file for dielectronic recombination included. It was used for regression testing for runs with _DR in the parameter file names clist_K : This file was used for a reasonably short time - assume only py70 will work - it is for dielectronic recombination.

atomic73 - z.atomic73.121218.tar.gz - NSH This is a set of data assembled after the work in 2012 to improve the agreement between python and cloudy. This was achieved by improving the calculation of recombination to ground state by included all the data needed to compute it from the raw data (recomb to all and recomb to ground). The topbase data for hydrogen was expended to include all available data and topbase data for iron was incoporated. elem_ions_ver.py - still only 14 elements included. The multiplicity of bare ions has also been corrected from 2 to 1. topbase_levels_h.py - More levels have been included from topbase, and the file levels_hhe file split into two. topbase_levels_fe.py - Added levels_ver_2.py - In 39, an error in the parse routine meant that many levels were missing. This is fixed lines_linked_ver_2.py - As above topbase_h1_phot.py - More data included topbase_fe_phot.py - Added chianti_dr.dat - dielectronic recombination data included from Chianti chianti_rr.dat - radiative recombination rate from chianti Badnell_GS_RR.txt - ground state recombination rate data from Nigel Badnells site at the university of strathclyde gffint.dat - gaunt free free factors from Sutherland (1997)