According to the documentation defining something like:
map http://a.com http://b.com @plugin=regex_remap.so @pparam=maps.reg
will redirect to http://b.com if none if the rules in maps.reg matches.
However, I've seen that if we instead of http://b.com/ writes http://b.com/default the word default gets prepended to the string being matched. I would expect the "fall through url" to be totally ignored before matching has been done.