Documentation of the libpciaccess API's can be generated from the sources via the doxygen command. Information about porting Xorg drivers to libpciaccess is located at:
https://www.x.org/wiki/PciReworkHowto
For historical reference, the original proposal for this work is at:
https://www.x.org/wiki/PciReworkProposal
All questions regarding this software should be directed at the Xorg mailing list:
https://lists.x.org/mailman/listinfo/xorg
The primary development code repository can be found at:
https://gitlab.freedesktop.org/xorg/lib/libpciaccess
Please submit bug reports and requests to merge patches there.
For patch submission instructions, see:
https://www.x.org/wiki/Development/Documentation/SubmittingPatches