I have experienced this behavior on two separate computers and while running the Live CD. I open Nemo, click on Networks in the left menu. Then I double click on Windows Network to browse it and Nemo completely crashes, taking all the desktop icons along with it. When I open Nemo again, the desktop icons come back and the same behavior of crashing when trying to open the Windows Network occurs. I can successfully access Windows network shares by going directly to the address in Nemo (smb://192.168.1.10/Share).
There are others who experience this. Others have tried Dolphin or another file explorer and they don't have the problem. Something is wrong with Nemo. On Mint 15, I did not have this issue.