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It took me a while to realize this so I wanted to make a note in the docs for myself in the future and others uses.
I was playing with pint-xarray and I couldn't work out why I couldn't round trip a file (xarray-contrib/pint-xarray#109). It turns out the DataArray had an enconding attribute which was being used (and overriding my unit conversion). In addition, I was also scratching my head for a while as to where my zarr store was getting chunks from which didn't correspomd to my numpy array (#5407).
This PR just makes a note of the importance of encoding attribute of DataArray(s) when writing to a zarr store.
docs page change is here: https://xray--5427.org.readthedocs.build/en/5427/generated/xarray.Dataset.to_zarr.html?highlight=zarr#xarray.Dataset.to_zarr