Improve pathname2url() and url2pathname() docs (#127125)

These functions have long sown confusion among Python developers. The
existing documentation says they deal with URL path components, but that
doesn't fit the evidence on Windows:

    >>> pathname2url(r'C:\foo')
    '///C:/foo'
    >>> pathname2url(r'\\server\share')
    '////server/share'  # or '//server/share' as of quite recently

If these were URL path components, they would imply complete URLs like
`file://///C:/foo` and `file://////server/share`. Clearly this isn't right.
Yet the implementation in `nturl2path` is deliberate, and the 
`url2pathname()` function correctly inverts it.

On non-Windows platforms, the behaviour until quite recently is to simply
quote/unquote the path without adding or removing any leading slashes. This
behaviour is compatible with *both* interpretations -- 1) the value is a
URL path component (existing docs), and 2) the value is everything
following `file:` (this commit)

The conclusion I draw is that these functions operate on everything after
the `file:` prefix, which may include an authority section. This is the
only explanation that fits both the  Windows and non-Windows behaviour.
It's also a better match for the function names.

Doc/library/urllib.request.rst

@@ -148,9 +148,15 @@ The :mod:`urllib.request` module defines the following functions:
 
 .. function:: pathname2url(path)
 
-   Convert the pathname *path* from the local syntax for a path to the form used in
-   the path component of a URL.  This does not produce a complete URL.  The return
-   value will already be quoted using the :func:`~urllib.parse.quote` function.
+   Convert the given local path to a ``file:`` URL. This function uses
+   :func:`~urllib.parse.quote` function to encode the path. For historical
+   reasons, the return value omits the ``file:`` scheme prefix. This example
+   shows the function being used on Windows::
+
+      >>> from urllib.request import pathname2url
+      >>> path = 'C:\\Program Files'
+      >>> 'file:' + pathname2url(path)
+      'file:///C:/Program%20Files'
 
    .. versionchanged:: 3.14
       Windows drive letters are no longer converted to uppercase.
@@ -161,11 +167,17 @@ The :mod:`urllib.request` module defines the following functions:
       found in any position other than the second character.
 
 
-.. function:: url2pathname(path)
+.. function:: url2pathname(url)
+
+   Convert the given ``file:`` URL to a local path. This function uses
+   :func:`~urllib.parse.unquote` to decode the URL. For historical reasons,
+   the given value *must* omit the ``file:`` scheme prefix. This example shows
+   the function being used on Windows::
 
-   Convert the path component *path* from a percent-encoded URL to the local syntax for a
-   path.  This does not accept a complete URL.  This function uses
-   :func:`~urllib.parse.unquote` to decode *path*.
+      >>> from urllib.request import url2pathname
+      >>> url = 'file:///C:/Program%20Files'
+      >>> url2pathname(url.removeprefix('file:'))
+      'C:\\Program Files'
 
    .. versionchanged:: 3.14
       Windows drive letters are no longer converted to uppercase.